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Substrate- and base-dependent reactivities of acylketene toward aryl aldimines derived from 2-amino-4-methylpyridine

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dc.contributor.authorOcal, Nuket
dc.contributor.authorMor, Necla
dc.contributor.authorErden, Ihsan
dc.date.accessioned2026-06-27T13:43:34Z
dc.date.issued2015
dc.description.abstractAcylketene, generated from 2,2,6-trimethyl-4H-1,3-dioxin-4-one reacts with aryl aldimines derived from 4-methyl-2-aminopyridine to give a variety of products, depending on the substituent on the C-aryl group, base used, and hydrolytic stability of the starting aldimine. Also the presence of the N-(2-pyridyl) group plays an important role in the fate of the reaction course, frequently participating in intramolecular conjugate additions, giving rise to interesting heterocycles. (C) 2015 Elsevier Ltd. All rights reserved.en
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [112T880]
dc.description.sponsorshipNational Institutes of Health [SC1GM082340]
dc.description.urihttps://doi.org/10.1016/j.tetlet.2015.09.157
dc.identifier.doi10.1016/j.tetlet.2015.09.157
dc.identifier.endpage6471
dc.identifier.issn0040-4039
dc.identifier.issue46
dc.identifier.startpage6468
dc.identifier.urihttps://hdl.handle.net/20.500.14981/54521
dc.identifier.volume56
dc.identifier.wos000364436300041
dc.language.isoeng
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD
dc.relation.ispartofTETRAHEDRON LETTERS
dc.subjectAldimines
dc.subjectAcylketene
dc.subject2,2,6-Trimethyl-4H-1,3-dioxin-4-one
dc.subjectSchiff base
dc.subject3,4-Dihydro-2H-pyrido[1,2-a]pyrimidin-2-one
dc.subjectTRANSFORMATIONS
dc.subjectDERIVATIVES
dc.subjectChemistry
dc.titleSubstrate- and base-dependent reactivities of acylketene toward aryl aldimines derived from 2-amino-4-methylpyridine
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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