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THERMODYNAMIC INTERACTIONS AND CHARACTERIZATION OF POLY(P-CHLOROSTYRENE) WITH SOME ALIPHATIC AND AROMATIC PROBES BY INVERSE GAS-CHROMATOGRAPHY

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dc.contributor.authorYILMAZ, F
dc.contributor.authorCANKURTARAN, OG
dc.contributor.authorBAYSAL, BM
dc.contributor.institutionauthorCANKURTARAN, Özlem
dc.date.accessioned2026-06-27T12:58:07Z
dc.date.issued1992
dc.description.abstractSome thermodynamic quantities were obtained for the interactions of poly (p-chlorostyrene) with n-pentane, n-hexane, n-heptane, benzene, toluene, isopropylbenzene and n-propylbenzene by the inverse gas chromatography method in the temperature range 150-170-degrees-C. The specific retention volumes (V(g)0), weight fraction activity coefficients of solute probes at infinite dilution (OMEGA1infinity), Flory-Huggins thermodynamic interaction parameters (chi12infinity), interaction parameters based on hard-core volumes (chi12*), effective exchange interaction parameters (X12BAR) of the equation of state theory, between polymer and solutes are given. The molar enthalpy of sorption (DELTAH(s)BAR), the partial molar heat of mixing at infinite dilution (DELTAH-1infinityBAR) and the solubility parameter of polymer (delta2) were also calculated.en
dc.description.urihttps://doi.org/10.1016/0032-3861(92)90414-r
dc.identifier.doi10.1016/0032-3861(92)90414-r
dc.identifier.endpage4568
dc.identifier.issn0032-3861
dc.identifier.issue21
dc.identifier.startpage4563
dc.identifier.urihttps://hdl.handle.net/20.500.14981/48314
dc.identifier.volume33
dc.identifier.wosA1992JX12700017
dc.language.isoeng
dc.publisherELSEVIER SCI LTD
dc.relation.ispartofPOLYMER
dc.subjectPOLY(P-CHLOROSTYRENE)
dc.subjectINVERSE GAS CHROMATOGRAPHY
dc.subjectPOLYMER SOLVENT INTERACTIONS
dc.subjectEQUATION OF STATE PARAMETERS
dc.subjectPOLYSTYRENE SOLUTIONS
dc.subjectPOLYMERS
dc.subjectPolymer Science
dc.titleTHERMODYNAMIC INTERACTIONS AND CHARACTERIZATION OF POLY(P-CHLOROSTYRENE) WITH SOME ALIPHATIC AND AROMATIC PROBES BY INVERSE GAS-CHROMATOGRAPHY
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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