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Photoinitiated polymerization of β-cyclodextrin/methyl methacrylate host/guest complex in the presence of water soluble photoinitiator, thioxanthone-catechol-O,O'-diacetic acid

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2010

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ARSU, Nergis

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SPRINGER

DOI

10.1007/s10847-010-9760-1

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Article
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Abstract

beta-Cyclodextrin (beta-CD) was used to complex the monomer, methyl methacrylate (MMA), yielding a water-soluble host/guest complex. Photoinitiated polymerization of beta-CD/MMA complex was achieved in the presence of thioxanthone-catechol-O,O'-diacetic acid (TX-Ct), a one component water soluble photoinitiator. Photodecarboxylation of TX-Ct in water seems to be an important reaction mechanism. Therefore, resulting alkyl radicals are able to initiate the polymerization of beta-CD/MMA host/guest complex in water.

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JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY

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1388-3127

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Keywords

Photopolymerization , Free radical polymerization , beta-Cyclodextrin , Thioxanthone , Water soluble photoinitiator , FREE-RADICAL POLYMERIZATION , METHYL-METHACRYLATE , AQUEOUS PHOTOPOLYMERIZATION , STYRENE , UNITS , Chemistry

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https://hdl.handle.net/20.500.14981/47721

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