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THE RETENTION DIAGRAM OF POLY(P-CHLOROSTYRENE) AND TERT-BUTYL ACETATE BY THE INVERSE GAS-CHROMATOGRAPHY METHOD

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dc.contributor.authorCANKURTARAN, O
dc.contributor.authorYILMAZ, F
dc.contributor.institutionauthorYILMAZ, Ayçe Feride
dc.contributor.institutionauthorCANKURTARAN, Özlem
dc.date.accessioned2026-06-27T12:56:39Z
dc.date.issued1993
dc.description.abstractThe retention diagram of poly(p-chlorostyrene) for tert-butyl acetate was obtained by the inverse gas chromatograhy method. This polymer-solvent pair exhibits a lower critical solution temperature, i.e., the solubility of the polymer in the solvent decreases with temperature. The obtained retention diagram of this polymer-solvent system contained an extra region with a negative slope at temperatures lower than 90-degrees-C. It appears that in this region, the favorable specific interactions between the polymer and the solvent can be observed. The weight fraction activity coefficient OMEGA1 infinity and the Flory-Huggins interaction parameter chi12infinity at infinite dilution and the effective exchange interation parameter chi12BAR of the system were calculated. These values confirm that the tert-butyl acetate is a poor solvent for this polymer, at 160-degrees-C.en
dc.identifier.endpage172
dc.identifier.issn1060-1325
dc.identifier.startpage167
dc.identifier.urihttps://hdl.handle.net/20.500.14981/47975
dc.identifier.volumeA30
dc.identifier.wosA1993KC28300020
dc.language.isoeng
dc.publisherMARCEL DEKKER INC
dc.relation.ispartofJOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
dc.subjectPolymer Science
dc.titleTHE RETENTION DIAGRAM OF POLY(P-CHLOROSTYRENE) AND TERT-BUTYL ACETATE BY THE INVERSE GAS-CHROMATOGRAPHY METHOD
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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