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Synthesis and EPR studies of soluble vanadyl octakis(4-tert-butylbenzylthio) porphyrazine

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dc.contributor.authorKeskin, Bahadir
dc.contributor.authorYerli, Yusuf
dc.contributor.authorAvciata, Ulvi
dc.contributor.institutionauthorKESKİN, Bahadır
dc.date.accessioned2026-06-27T13:21:36Z
dc.date.issued2013
dc.description.abstractMagnesium porphyrazinate substituted with eight 4-tert-butylphenylthio-groups on peripheral positions has been synthesized by cyclotetramerization of 1,2-bis(4-t-butylphenylthio)maleonitrile in the presence of magnesium butanolate. The metal-free derivative was obtained by treatment with trifluoroacetic acid and further reaction of this product with vanadyl(IV) sulfate led to the vanadyl porphyrazinate. These new compounds have been characterized by elemental analysis, together with FTIR, and UV-vis spectral data. The magnetic properties of the complex have been investigated by electron paramagnetic resonance spectroscopy.en
dc.description.sponsorshipResearch Fund of the Yildiz Technical University [2012-01-02-GEP08]
dc.description.urihttps://doi.org/10.1080/00958972.2013.811496
dc.identifier.doi10.1080/00958972.2013.811496
dc.identifier.eissn1029-0389
dc.identifier.endpage2622
dc.identifier.issn0095-8972
dc.identifier.issue15
dc.identifier.startpage2615
dc.identifier.urihttps://hdl.handle.net/20.500.14981/52172
dc.identifier.volume66
dc.identifier.wos000321814600004
dc.language.isoeng
dc.publisherTAYLOR & FRANCIS LTD
dc.relation.ispartofJOURNAL OF COORDINATION CHEMISTRY
dc.subjectPorphyrazine
dc.subjectVanadyl(IV) sulfate
dc.subjectEPR
dc.subjectSINGLE-CRYSTALS
dc.subjectOPTICAL-PROPERTIES
dc.subjectMETAL-COMPLEXES
dc.subjectPHTHALOCYANINES
dc.subjectVO2+
dc.subjectSUBSTITUENTS
dc.subjectCHEMISTRY
dc.subjectLIGANDS
dc.subjectSYSTEM
dc.subjectNI(II)
dc.titleSynthesis and EPR studies of soluble vanadyl octakis(4-tert-butylbenzylthio) porphyrazine
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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