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Photophysical and photochemical properties of a zinc phthalocyanine with four diphenylborinic ester moieties

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dc.contributor.authorOzcelik, Sennur
dc.contributor.authorKaraoglan, Gulnur Keser
dc.contributor.authorGumrukcu, Gulsah
dc.contributor.authorErdogmus, Ali
dc.contributor.authorGul, Ahmet
dc.date.accessioned2026-06-27T13:30:56Z
dc.date.issued2014
dc.description.abstractA novel zinc(II) phthalocyanine substituted with four diphenylborinic ester units was synthesized by the reaction of 2,9,16,23-tetra (salicylaldimino)-phthtalocyaninatozinc(II) and triphenylborane in THF at reflux condition. The novel zinc phthalocyanine was characterized by using elemental analysis, IR, H-1 and 11B-NMR and UV-Vis spectral data. B-11-NMR data demonstrated that the boron atom is in tetracoordinated state and diphenylborinate substituents have a cyclic structure with a coordinative N-B bond enhancing the stability of this borinated phthalocyanine derivative. Moreover, the consequences of the presence of diphenylborinic ester groups on the spectral, photophysical and photochemical properties of the new zinc phthalocyanine are investigated in detail. (c) 2014 Elsevier B.V. All rights reserved.en
dc.description.sponsorshipResearch Fund of Istanbul Technical University
dc.description.sponsorshipTUBITAK [110T833]
dc.description.sponsorshipTurkish Academy of Sciences (TUBA)
dc.description.urihttps://doi.org/10.1016/j.jorganchem.2014.06.024
dc.identifier.doi10.1016/j.jorganchem.2014.06.024
dc.identifier.eissn1872-8561
dc.identifier.endpage23
dc.identifier.issn0022-328X
dc.identifier.startpage17
dc.identifier.urihttps://hdl.handle.net/20.500.14981/53434
dc.identifier.volume769
dc.identifier.wos000342569200004
dc.language.isoeng
dc.publisherELSEVIER SCIENCE SA
dc.relation.ispartofJOURNAL OF ORGANOMETALLIC CHEMISTRY
dc.subjectPhthalocyanine
dc.subjectDiphenylborinic acid
dc.subjectSchiff base
dc.subjectBorinate complex
dc.subjectPhotochemistry
dc.subjectFluorescence
dc.subjectMETAL-COMPLEXES
dc.subjectELECTROLUMINESCENCE
dc.subjectSUBSTITUENTS
dc.subjectDERIVATIVES
dc.subjectChemistry
dc.titlePhotophysical and photochemical properties of a zinc phthalocyanine with four diphenylborinic ester moieties
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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