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Chiral polymorphism in new imine based rod-like liquid crystals

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dc.contributor.authorCaglar, Fatma Pinar
dc.contributor.authorAkdas-Kilic, Huriye
dc.contributor.authorOcak, Hale
dc.contributor.authorEran, Belkiz Bilgin
dc.date.accessioned2026-06-27T14:25:36Z
dc.date.issued2020
dc.description.abstractNew imine based rod-like compounds, composed of three-benzene-ring molecular core linked with azomethine as well as ester groups and terminated with (S)-3,7-dimethyloctyloxy chiral unit at one side have been synthesized. The other terminal position has been varied by using n-octyloxy/decyloxy/dodecyloxy groups to reveal chain length effect on mesophase behavior. The liquid crystalline properties of the new compounds have been investigated by polarizing optical microscopy, differential scanning calorimetry and electro-optic studies. The novel chiral calamitics derived from Schiff base or salicylaldimine-core show a chiral polymorphism comprising of blue phase and chiral nematic as well as smectics such as chiral tilted smectic and unidentified smectic mesophase. (C) 2020 Elsevier B.V. All rights reserved.en
dc.description.sponsorshipYildiz Technical University Scientific Research Projects Coordination Department [FBA-2017-3056]
dc.description.sponsorshipTUBITAK [TUBITAK-2232]
dc.description.urihttps://doi.org/10.1016/j.molstruc.2020.128755
dc.identifier.doi10.1016/j.molstruc.2020.128755
dc.identifier.eissn1872-8014
dc.identifier.issn0022-2860
dc.identifier.urihttps://hdl.handle.net/20.500.14981/60492
dc.identifier.volume1220
dc.identifier.wos000573567000001
dc.language.isoeng
dc.publisherELSEVIER
dc.relation.ispartofJOURNAL OF MOLECULAR STRUCTURE
dc.subjectImine
dc.subjectRod-like liquid crystals
dc.subjectChiral mesophases
dc.subjectPolymorphism
dc.subjectBLUE PHASES
dc.subjectCROSS-OVER
dc.subjectCOMPLEXES
dc.subjectPALLADIUM(II)
dc.subjectPOLARIZATION
dc.subjectMOLECULES
dc.subjectLIGANDS
dc.subjectSOFT
dc.subjectChemistry
dc.titleChiral polymorphism in new imine based rod-like liquid crystals
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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