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Synthesis and photooxygenation of homochiral 2-methylpyrrole derivatives of chiral amino alcohols: simple, selective access to chiral bicyclic lactams

dc.contributor.authorAydogan, F
dc.contributor.authorDemir, AS
dc.date.accessioned2026-06-27T12:59:19Z
dc.date.issued2004
dc.description.abstractHomochiral 2-methylpyrrole derivatives are synthesized in high yields starting from chiral amino alcohols and 5-chloro-3-pentene-2-one. The photooxygenation of these compounds in the presence of a photosynthesizer furnishes the pyrrolooxazolone structures in high diastereoselectivities. In all of the examples, trans-isomers are formed as the major products. (C) 2003 Elsevier Ltd. All rights reserved.en
dc.description.urihttps://doi.org/10.1016/j.tetasy.2003.11.011
dc.identifier.doi10.1016/j.tetasy.2003.11.011
dc.identifier.endpage265
dc.identifier.issn0957-4166
dc.identifier.issue2
dc.identifier.startpage259
dc.identifier.urihttps://hdl.handle.net/20.500.14981/48619
dc.identifier.volume15
dc.identifier.wos000188499100014
dc.language.isoeng
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD
dc.relation.ispartofTETRAHEDRON-ASYMMETRY
dc.subjectSINGLET OXYGEN OXIDATION
dc.subjectDIELS-ALDER REACTIONS
dc.subjectQUATERNARY CARBON-COMPOUNDS
dc.subjectASYMMETRIC TOTAL SYNTHESIS
dc.subjectALPHA,BETA-UNSATURATED LACTAMS
dc.subjectFACILE SYNTHESIS
dc.subjectPYRROLES
dc.subjectACID
dc.subjectCYCLOPROPANES
dc.subjectANALOGS
dc.subjectChemistry
dc.titleSynthesis and photooxygenation of homochiral 2-methylpyrrole derivatives of chiral amino alcohols: simple, selective access to chiral bicyclic lactams
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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