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Derivatization and in situ metallation of phthalocyanines using click chemistry

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dc.contributor.authorYilmaz, Yusuf
dc.contributor.authorSener, M. Kasim
dc.contributor.authorErden, Ibrahim
dc.contributor.authorAvciata, Ulvi
dc.date.accessioned2026-06-27T13:06:14Z
dc.date.issued2009
dc.description.abstractDialkyl (3,4-dicyanophenyl)propargylmalonates were prepared by the reaction of propargyl bromide and the potassium salt of dialkyl-3,4-dicyanophenylmalonates. A cyclotetramerization reaction was achieved in pentanol in the presence of DBU without protective/deprotective chemistry, affording the peripherally tetrasubstituted alkynyl phthalocyanines. Subsequently, in situ metallation and 'clicking' were employed for the first time as an efficient and quantitative route to tetratriazole-functionalized phthalocyanines. (c) 2009 Elsevier Ltd. All rights reserved.en
dc.description.sponsorshipYildiz Technical University
dc.description.urihttps://doi.org/10.1016/j.poly.2009.07.033
dc.identifier.doi10.1016/j.poly.2009.07.033
dc.identifier.endpage3424
dc.identifier.issn0277-5387
dc.identifier.issue16
dc.identifier.startpage3419
dc.identifier.urihttps://hdl.handle.net/20.500.14981/49768
dc.identifier.volume28
dc.identifier.wos000271781200003
dc.language.isoeng
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD
dc.relation.ispartofPOLYHEDRON
dc.subjectClick chemistry
dc.subjectPhthalocyanine
dc.subjectSupramolecular association
dc.subjectMetallation
dc.subjectNANOCRYSTALLINE TIO2 FILMS
dc.subjectSOLUBLE PHTHALOCYANINES
dc.subjectZINC PHTHALOCYANINES
dc.subjectEFFICIENT
dc.subjectWATER
dc.subjectSENSITIZATION
dc.subjectCOMPLEXES
dc.subjectTHERAPY
dc.subjectCOBALT
dc.subjectROUTE
dc.subjectChemistry
dc.subjectCrystallography
dc.titleDerivatization and in situ metallation of phthalocyanines using click chemistry
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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