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Photoinitiated free radical polymerization of methylmethacrylate by using of quinoxalines in the presence of aldehydes

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dc.contributor.authorAydin, Meral
dc.contributor.authorArsu, Nergis
dc.contributor.institutionauthorAYDIN, Meral
dc.contributor.institutionauthorARSU, Nergis
dc.date.accessioned2026-06-27T13:00:30Z
dc.date.issued2006
dc.description.abstractA series of quinoxalines at different concentrations were used in the presence of benzaldehyde (BA) and phthaldialdehyde (PDA) to initiate the polymerization of methylmethacrylate (MMA) formulation containing 2-ethyl-2-(hydroxymethyl)-1,3-propanediol-trimethylmethacrylate (TMPTMA) as a multifunctional acrylate. Highest conversion percentage of polymerization of MMA were obtained in the presence of benzaldehyde when diphenylquinoxaline, phenanthroquinoxaline and acenaphthoquinoxaline were used as an initiator. In the case of benzaldehyde, benzoyl radical were possibly responsible for the initiation of polymerization where quinoxalines do not initiate polymerization of acrylates in the presence of oxygen. (C) 2006 Elsevier B.V. All rights reserved.en
dc.description.urihttps://doi.org/10.1016/j.porgcoat.2006.06.006
dc.identifier.doi10.1016/j.porgcoat.2006.06.006
dc.identifier.endpage342
dc.identifier.issn0300-9440
dc.identifier.issue4
dc.identifier.startpage338
dc.identifier.urihttps://hdl.handle.net/20.500.14981/48908
dc.identifier.volume56
dc.identifier.wos000239867800010
dc.language.isoeng
dc.publisherELSEVIER SCIENCE SA
dc.relation.ispartofPROGRESS IN ORGANIC COATINGS
dc.subjectphotopolymerization
dc.subjectfree radical polymerization
dc.subjectquinoxaline
dc.subjectRT-FTIR
dc.subjectDECARBOXYLATION
dc.subjectChemistry
dc.subjectMaterials Science
dc.titlePhotoinitiated free radical polymerization of methylmethacrylate by using of quinoxalines in the presence of aldehydes
dc.typeReview
dspace.entity.typePublication
local.import.sourceWOS

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