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Biomimetic crystallization of calcium carbonate in the presence of water-soluble zwitterionic block copolymer

dc.contributor.authorYazici, Ozlem
dc.contributor.authorKaraman, Ferdane
dc.date.accessioned2026-06-27T14:20:06Z
dc.date.issued2019
dc.description.abstractCrystallization of calcium carbonate (CC) in aqueous solutions by gas-liquid diffusion procedure was investigated systematically in the presence of poly(4-sulfonic acid diphenylamine)-block-poly(ethylene glycol) (PSDA-b-PEG), wherein the PSDA block is a polymeric zwitterion. PSDA-b-PEG was synthesized with the reaction of tosylated PEG and amine-functionalized PSDA and was characterized by nuclear magnetic resonance. The parameters such as, block copolymer concentration, crystallization time and initial pH were considered as indicators of block copolymer's capability in controlling the morphology of CC particles(.) The particles were characterized by Fourier transform infrared, scanning electron microscopy, and X-ray diffraction. The results suggest that PSDA-b-PEG is a suitable template to control the growth mechanism of CC to produce meso-sized particles with different morphologies. POLYM. ENG. SCI., 59:96-102, 2019. (c) 2018 Society of Plastics Engineersen
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [107T697]
dc.description.sponsorshipTUBITAK Directorate of Science Fellowships and Grant Programmes (BIDEB)-2211
dc.description.sponsorshipScientific Research Projects Coordination Center, Yildiz Technical University [29-01-02-DOP03]
dc.description.urihttps://doi.org/10.1002/pen.24871
dc.identifier.doi10.1002/pen.24871
dc.identifier.eissn1548-2634
dc.identifier.endpage102
dc.identifier.issn0032-3888
dc.identifier.issue1
dc.identifier.startpage96
dc.identifier.urihttps://hdl.handle.net/20.500.14981/59386
dc.identifier.volume59
dc.identifier.wos000454766600011
dc.language.isoeng
dc.publisherWILEY
dc.relation.ispartofPOLYMER ENGINEERING AND SCIENCE
dc.rightsopenAccess
dc.subjectDENSITY POLYETHYLENE
dc.subjectCRYSTAL PHASE
dc.subjectAMINO-ACIDS
dc.subjectCACO3
dc.subjectPOLYPROPYLENE
dc.subjectMORPHOGENESIS
dc.subjectMESOCRYSTALS
dc.subjectMORPHOLOGIES
dc.subjectAGGREGATION
dc.subjectPOLYMORPHS
dc.subjectEngineering
dc.subjectPolymer Science
dc.titleBiomimetic crystallization of calcium carbonate in the presence of water-soluble zwitterionic block copolymer
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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