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Biphenyl Based Non-symmetrical Bent-Core Mesogens Containing a Chiral Moiety and an Olefinic End Group

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dc.contributor.authorOcak, Hale
dc.contributor.authorBilgin-Eran, Belkiz
dc.contributor.institutionauthorOCAK GÜMRÜKÇÜ, Hale
dc.date.accessioned2026-06-27T13:37:03Z
dc.date.issued2015
dc.description.abstractNew nonsymmetrical bent-core compounds consisting of a biphenyl-3,4 '-diol central unit, a chiral terminal chain and an olefinic end group at the other terminus have been synthesized and characterized to study the influence of a chiral moiety, the length of terminal alkenyl chain, and the number of aromatic rings in the rod-like wings which are substituted at the 3- and 4-position of central biphenyl core on mesophase properties of bent-core mesogens. The liquid crystalline properties of the compounds were investigated by differential scanning calorimetry, optical polarizing microscopy, and electro-optic methods. Depending on the length of the olefinic chain and the number of aromatic rings in the rod-like wings, the bent-core compounds with a chiral moiety show B-1 type mesophase, polar smectic C phase (SmCP) or nonmesomorphic behavior.en
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [107T395]
dc.description.urihttps://doi.org/10.1080/15421406.2014.953746
dc.identifier.doi10.1080/15421406.2014.953746
dc.identifier.eissn1563-5287
dc.identifier.endpage30
dc.identifier.issn1542-1406
dc.identifier.issue1
dc.identifier.startpage19
dc.identifier.urihttps://hdl.handle.net/20.500.14981/53773
dc.identifier.volume609
dc.identifier.wos000352900300003
dc.language.isoeng
dc.publisherTAYLOR & FRANCIS LTD
dc.relation.ispartofMOLECULAR CRYSTALS AND LIQUID CRYSTALS
dc.subjectchiral moiety
dc.subjectolefinic end group
dc.subjectliquid crystals
dc.subjectrod-like wings
dc.subjectBent-core mesogens
dc.subjectLIQUID-CRYSTALLINE PHASES
dc.subjectCROSS-COUPLING REACTIONS
dc.subjectMESOMORPHIC PROPERTIES
dc.subjectACHIRAL MOLECULES
dc.subjectPOLAR ORDER
dc.subjectMESOPHASE
dc.subjectBEHAVIOR
dc.subjectSYSTEMS
dc.subjectCHAINS
dc.subjectACIDS
dc.subjectChemistry
dc.subjectCrystallography
dc.subjectMaterials Science
dc.titleBiphenyl Based Non-symmetrical Bent-Core Mesogens Containing a Chiral Moiety and an Olefinic End Group
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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