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Synthesis and boron interaction of new amino acid containing phthalocyanines and the precursor

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dc.contributor.authorBaseren, Sukran Cenikli
dc.contributor.authorErdogmus, Ali
dc.contributor.authorGul, Ahmet
dc.date.accessioned2026-06-27T14:15:24Z
dc.date.issued2018
dc.description.abstractA new phthalonitrile precursor with tyrosine substituent and the zinc phthalocyanine derived from it were synthesized and their interaction with diphenylborinic acid was studied. The new compounds were characterized by using elemental analysis, IR, H-1 and B-11-NMR and UV-VIS spectral data. B-11-NMR data demonstrated that boron atom attached to the phthalonitrile precursor is in a bulky tetra-coordinated state with the formation of a coordinative N-B bond while completely planar phthalocyanine moieties with high aggregation tendencies at the concentrations used in NMR measurements lead the borinic ester side of the molecule into a planar tri-coordinated form. Moreover, the consequences of the presence of diphenylborinic ester groups on the spectral, photophysical and photochemical properties of the new zinc phthalocyanine are investigated in detail. (C) 2018 Elsevier B.V. All rights reserved.en
dc.description.sponsorshipResearch Fund of the Technical University of Istanbul
dc.description.sponsorshipTurkish Academy of Sciences (TUBA)
dc.description.urihttps://doi.org/10.1016/j.jorganchem.2018.04.016
dc.identifier.doi10.1016/j.jorganchem.2018.04.016
dc.identifier.eissn1872-8561
dc.identifier.endpage111
dc.identifier.issn0022-328X
dc.identifier.startpage105
dc.identifier.urihttps://hdl.handle.net/20.500.14981/58521
dc.identifier.volume866
dc.identifier.wos000432600900013
dc.language.isoeng
dc.publisherELSEVIER SCIENCE SA
dc.relation.ispartofJOURNAL OF ORGANOMETALLIC CHEMISTRY
dc.subjectPhthalocyanine
dc.subjectDiphenylborinic acid
dc.subjectBorinate complex
dc.subjectPhotochemistry
dc.subjectFluorescence
dc.subjectZINC PHTHALOCYANINE
dc.subjectPHOTOCHEMICAL PROPERTIES
dc.subjectCOMPLEXES
dc.subjectESTER
dc.subjectChemistry
dc.titleSynthesis and boron interaction of new amino acid containing phthalocyanines and the precursor
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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