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SYNTHESIS, CHARACTERIZATION AND KINETICS OF THERMAL-DECOMPOSITION OF VARIOUS PEROXYCARBAMATES AND THEIR INITIATION OF METHYL-METHACRYLATE POLYMERIZATION

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dc.contributor.authorYILDIRIM, H
dc.contributor.authorBAYSAL, BM
dc.contributor.institutionauthorBAYSAL, Mustafa
dc.date.accessioned2026-06-27T12:58:07Z
dc.date.issued1990
dc.description.abstractSeveral dimeric and polymeric peroxycarbamates were synthesized using various aliphatic diisocyanates and hydroperoxides. The products were characterized by IR spectroscopy, molecular weight measurements, isocyanate and peroxide analyses. Thermal decomposition kinetics of these peroxycarbamates were studied in 1,4-dioxane or toluene solutions at 80, 90, and 100-degrees-C. All reactions were found to proceed according to a first-order kinetics with activation energies in the range of 126-144 kJ/mol, depending on the structure of the peroxycarbamate. One of the polymeric products was used to initiate methyl methacrylate polymerization at 80-degrees-C in bulk. The initiating activity of this peroxycarbamate was found to be better than that of some hydroperoxides.en
dc.description.urihttps://doi.org/10.1002/apmc.1990.051810109
dc.identifier.doi10.1002/apmc.1990.051810109
dc.identifier.endpage117
dc.identifier.issn0003-3146
dc.identifier.startpage103
dc.identifier.urihttps://hdl.handle.net/20.500.14981/48315
dc.identifier.volume181
dc.identifier.wosA1990FA60600009
dc.language.isoeng
dc.publisherHUTHIG & WEPF VERLAG
dc.relation.ispartofANGEWANDTE MAKROMOLEKULARE CHEMIE
dc.subjectBLOCK COPOLYMERS
dc.subjectSTYRENE
dc.subjectPolymer Science
dc.titleSYNTHESIS, CHARACTERIZATION AND KINETICS OF THERMAL-DECOMPOSITION OF VARIOUS PEROXYCARBAMATES AND THEIR INITIATION OF METHYL-METHACRYLATE POLYMERIZATION
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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