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Direct synthesis of imidazolidin-4-ones via cycloadditions of imines with a Leuchs' anyhdride

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dc.contributor.authorSucu, Bilgesu Onur
dc.contributor.authorOcal, Nuket
dc.contributor.authorErden, Ihsan
dc.date.accessioned2026-06-27T13:38:25Z
dc.date.issued2015
dc.description.abstractA new method for a one-step synthesis of imidazolidin-4-ones has been developed based on tandem nucleophilic additions-decarboxylation-intramolecular cyclizations of imines with a Leuchs' anhydride. Depending on the reaction conditions (with or without base), one either obtains the title compounds, or a-amino acid amide-derived Schiff bases. The latter have also been shown as useful precursors of a-amino acid amides by selective reduction of the imine bond with NaBH4 in the presence of p-T50H. (C) 2015 Elsevier Ltd. All rights reserved.en
dc.description.sponsorshipNational Institutes of Health [5C1GM082340]
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [112T880]
dc.description.sponsorshipDivision Of Chemistry
dc.description.sponsorshipDirect For Mathematical & Physical Scien [1228656] Funding Source: National Science Foundation
dc.description.urihttps://doi.org/10.1016/j.tetlet.2015.04.002
dc.identifier.doi10.1016/j.tetlet.2015.04.002
dc.identifier.endpage2592
dc.identifier.issn0040-4039
dc.identifier.issue20
dc.identifier.startpage2590
dc.identifier.urihttps://hdl.handle.net/20.500.14981/54053
dc.identifier.volume56
dc.identifier.wos000354139200013
dc.language.isoeng
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD
dc.relation.ispartofTETRAHEDRON LETTERS
dc.subjectLeuchs' anhydrides
dc.subjectalpha-Amino acid amides
dc.subjectImidazolidin-4-ones
dc.subjectSchiff bases
dc.subjectABSOLUTE-CONFIGURATIONS
dc.subjectNITROGEN ANALOGS
dc.subjectSCHIFF-BASES
dc.subjectANHYDRIDES
dc.subjectDERIVATIVES
dc.subjectPRIMAQUINE
dc.subjectCONDENSATION
dc.subject(+/-)-CORYNOLINE
dc.subjectSCOPE
dc.subjectChemistry
dc.titleDirect synthesis of imidazolidin-4-ones via cycloadditions of imines with a Leuchs' anyhdride
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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