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Reactions of the dianion obtained by reductive metallation of 3,4-diphenylcinnoline

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dc.contributor.authorÖcal, N
dc.contributor.authorTurgut, Z
dc.contributor.authorKaban, S
dc.contributor.institutionauthorTURGUT, Zühal
dc.date.accessioned2026-06-27T12:57:27Z
dc.date.issued1999
dc.description.abstractThe reductive metallation of 3,4-diphenylcinnoline (1) by sodium metal in tetrahydrofuran under an inert atmosphere to the monomeric dianion 2 has been explored, and the nucleophilicity of the disodium adduct towards various protonation, alkylation, and acylation reagents has been investigated. Generally, 2 reacts via its 1,4-positions forming 1,4-dihydro derivatives of 1.en
dc.identifier.endpage920
dc.identifier.issn0026-9247
dc.identifier.issue7
dc.identifier.startpage915
dc.identifier.urihttps://hdl.handle.net/20.500.14981/48153
dc.identifier.volume130
dc.identifier.wos000081584800009
dc.language.isoeng
dc.publisherSPRINGER-VERLAG WIEN
dc.relation.ispartofMONATSHEFTE FUR CHEMIE
dc.subjectalkylation
dc.subjectacylation
dc.subjectdianion
dc.subject3,4-diphenylcinnoline
dc.subjectreductive metallation
dc.subjectUNSATURATED HETEROCYCLIC-COMPOUNDS
dc.subjectALKALI-METALS
dc.subjectMETALATION
dc.subjectChemistry
dc.titleReactions of the dianion obtained by reductive metallation of 3,4-diphenylcinnoline
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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