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Reductive metallation of 6-methyl-2,3-diphenylquinoxaline. Synthesis of 1,4-dihydro-1,4-diazine derivatives

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dc.contributor.authorÖcal, N
dc.contributor.authorTurgut, Z
dc.contributor.authorKaban, S
dc.contributor.institutionauthorTURGUT, Zühal
dc.date.accessioned2026-06-27T12:56:46Z
dc.date.issued1998
dc.description.abstractThe reductive metallation of 6-methyl-2,3-diphenylquinoxaline 1 with sodium metal in tetrahydrofuran and inert atmosphere to a monomeric dianion 2 has been explored and the nucleophilicity of this disodium adduct was investigated with various alkylation and acylation reagents. An annulation of the pyrazine ring system was accomplished by treating the dianion with polymethylene chlorides, CI(CH2)(n)Cl, n = 3.4.en
dc.identifier.eissn1943-5193
dc.identifier.endpage1351
dc.identifier.issn0022-152X
dc.identifier.issue6
dc.identifier.startpage1349
dc.identifier.urihttps://hdl.handle.net/20.500.14981/48008
dc.identifier.volume35
dc.identifier.wos000078054500020
dc.language.isoeng
dc.publisherWILEY
dc.relation.ispartofJOURNAL OF HETEROCYCLIC CHEMISTRY
dc.subjectMETALATION
dc.subjectChemistry
dc.titleReductive metallation of 6-methyl-2,3-diphenylquinoxaline. Synthesis of 1,4-dihydro-1,4-diazine derivatives
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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