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Synthesis and liquid crystalline properties of new triazine-based π-conjugated macromolecules with chiral side groups

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dc.contributor.authorAkkurt, Nihat
dc.contributor.authorAl-Jumaili, Mohammed Hadi Ali
dc.contributor.authorOcak, Hale
dc.contributor.authorCakar, Fatih
dc.contributor.authorTorun, Lokman
dc.date.accessioned2026-06-27T14:29:20Z
dc.date.issued2020
dc.description.abstractIn this study, we reported the synthesis of a new tribranched macromolecule liquid crystal with triazine in the centre. The central triazine core is bonded via sequences of Sonigashira coupling to 3 triazine unites through acetylenic bridges. The triazines at the periphery are substituted with 2 chiral citronellyloxy side groups. The salt of the resulting star-shaped macromolecule, which was oily at room temperature, with 4-dodecyloxybenzoic acid at 1:1 ratio exhibited a Smectic C (SmC) mesophase. The liquid crystalline properties of organic salt were investigated using DSC (differential scanning calorimetry) and POM (polarizing optical microscopy).en
dc.description.sponsorshipTUBITAK [114Z722]
dc.description.sponsorshipYildiz Technical University [201501-01-DOP04]
dc.description.urihttps://doi.org/10.3906/kim-1912-51
dc.identifier.doi10.3906/kim-1912-51
dc.identifier.endpage+
dc.identifier.issn1300-0527
dc.identifier.issue3
dc.identifier.pubmed33488189
dc.identifier.startpage726
dc.identifier.urihttps://hdl.handle.net/20.500.14981/61191
dc.identifier.volume44
dc.identifier.wos000538115400014
dc.language.isoeng
dc.publisherTubitak Scientific & Technological Research Council Turkey
dc.relation.ispartofTURKISH JOURNAL OF CHEMISTRY
dc.rightsopenAccess
dc.subjectTriazine
dc.subjectionic liquid crystals
dc.subjecthydrogen bonding
dc.subjectstar-shaped triazine
dc.subjectSonogashira coupling
dc.subjectG PHASE
dc.subjectMOLECULES
dc.subjectMESOGENS
dc.subjectSERIES
dc.subjectChemistry
dc.subjectEngineering
dc.titleSynthesis and liquid crystalline properties of new triazine-based π-conjugated macromolecules with chiral side groups
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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