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A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting

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dc.contributor.authorBulut, Aysun
dc.contributor.authorWorle, Michael
dc.contributor.authorZorlu, Yunus
dc.contributor.authorKirpi, Erdogan
dc.contributor.authorKurt, Huseyin
dc.contributor.authorZubieta, Jon
dc.contributor.authorGrabowsky, Simon
dc.contributor.authorBeckmann, Jens
dc.contributor.authorYucesan, Gundog
dc.date.accessioned2026-06-27T14:02:55Z
dc.date.issued2017
dc.description.abstractThe reaction of appropriate copper and vanadium salts with tetratopic methane tetra-p-phenylphosphonic acid (MTPPA) in the presence of 2,2':6':2 ''-terpyridine (terpy) yielded the three-dimensional bimetallic copper vanadium phosphonate framework [{Cu(terpy)}(4)Cu(VO2)(4)(MTPPA-H)(2)]center dot 4H(2)O (1). Terpy has no net contribution to the three-dimensional structure providing a potential platform for void space formation via mold-casting. The structure was characterized by single-crystal X-ray diffraction and thermogravimetric analysis (TGA). Magnetic measurements were performed using a SQUID magnetometer. The crystal structure of the methanol solvate of the free ligand, MTPPA center dot MeOH, was analysed using Hirshfeld surfaces and fingerprint plots.en
dc.description.sponsorshipTUBITAK [212T060]
dc.description.sponsorshipCOST action [TD 1304]
dc.description.sponsorshipGerman Research Foundation [GR4451/1-1]
dc.description.urihttps://doi.org/10.1107/s2052520617000245
dc.identifier.doi10.1107/s2052520617000245
dc.identifier.endpage303
dc.identifier.issn2052-5206
dc.identifier.pubmed28362294
dc.identifier.startpage296
dc.identifier.urihttps://hdl.handle.net/20.500.14981/56761
dc.identifier.volume73
dc.identifier.wos000399007700022
dc.language.isoeng
dc.publisherINT UNION CRYSTALLOGRAPHY
dc.relation.ispartofACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS
dc.subjectmetal organic frameworks (MOFs)
dc.subjectorganophosphonate complexes
dc.subjectbimetallic Cu-V frameworks
dc.subjectHirshfeld surfaces
dc.subjectvoid space formation
dc.subjectMETAL-ORGANIC FRAMEWORKS
dc.subjectSTATE COORDINATION CHEMISTRY
dc.subjectSOLID-STATE
dc.subjectCRYSTAL-STRUCTURES
dc.subjectSTRUCTURAL-CHARACTERIZATION
dc.subjectSUPRAMOLECULAR CHEMISTRY
dc.subjectHYDROTHERMAL SYNTHESIS
dc.subjectPHOSPHONATES SYNTHESIS
dc.subjectBUILDING-BLOCK
dc.subjectV/P/O LAYERS
dc.subjectChemistry
dc.subjectCrystallography
dc.titleA potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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