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One-component bimolecular photoinitiating systems, 2 - Thioxanthone acetic acid derivatives as photoinitiators for free radical polymerization

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dc.contributor.authorAydin, M
dc.contributor.authorArsu, N
dc.contributor.authorYagci, Y
dc.contributor.institutionauthorAYDIN, Meral
dc.contributor.institutionauthorARSU, Nergis
dc.date.accessioned2026-06-27T12:59:12Z
dc.date.issued2003
dc.description.abstractThe compounds 2-thioxanthone-thioacetic acid and 2-(carboxymethoxy)thioxanthone, bimolecular photoinitiators for free radical polymerization, are synthesized and characterized. Their capability to act as initiators for the polymerization of methyl methacrylate was examined. The postulated mechanism is based on the intermolecular electron-transfer reaction of the excited photoinitiator with the sulfur or oxygen atom of the ground state of the respective photoinitiator followed by decarboxylation. The resulting alkyl radicals initiate the polymerization.en
dc.description.urihttps://doi.org/10.1002/marc.200300019
dc.identifier.doi10.1002/marc.200300019
dc.identifier.eissn1521-3927
dc.identifier.endpage723
dc.identifier.issn1022-1336
dc.identifier.issue12
dc.identifier.startpage718
dc.identifier.urihttps://hdl.handle.net/20.500.14981/48588
dc.identifier.volume24
dc.identifier.wos000185175600003
dc.language.isoeng
dc.publisherWILEY-V C H VERLAG GMBH
dc.relation.ispartofMACROMOLECULAR RAPID COMMUNICATIONS
dc.subjectelectron transfer
dc.subjectinitiators
dc.subjectphotopolymerization
dc.subjectradical polymerization
dc.subjectthioxanthone
dc.subjectPHOTOSENSITIZED DECARBOXYLATION
dc.subjectCARBOXYLIC-ACIDS
dc.subjectPolymer Science
dc.titleOne-component bimolecular photoinitiating systems, 2 - Thioxanthone acetic acid derivatives as photoinitiators for free radical polymerization
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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