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Peripherally and non-peripherally tetra-HBME (4-hydroxybenzyl methyl ether) substituted metal-free and zinc(II) phthalocyanines: Synthesis, characterization, and investigation of photophysical and photochemical properties

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dc.contributor.authorGunsel, Armagan
dc.contributor.authorBeylik, Sevde
dc.contributor.authorBilgicli, Ahmet T.
dc.contributor.authorAtmaca, Goknur Yasa
dc.contributor.authorErdogmus, Ali
dc.contributor.authorYarasir, M. Nilufer
dc.date.accessioned2026-06-27T14:11:48Z
dc.date.issued2018
dc.description.abstractThis paper reports on the synthesis and characterization of non-peripherally and peripherally tetrasubstituted metal-free and zinc(II) phthalocyanines functionalized with the phenolic compound 4-hydroxy-benzyl methyl ether (HBME). Synthesized compounds have been characterized by elemental analysis, FT-IR, H-1 NMR, C-13 NMR, MALDI-MS and UV-Vis spectral data. Besides, spectral, photophysical (fluorescence quantum yields and lifetimes) and photochemical (singlet oxygen generation and photodegradation under light irradiation) properties of newly synthesized phthalocyanines were investigated in DMF solution. We obtained very high singlet oxygen quantum yields as 0.86, 0.91, suggesting its potential as photosensitizer in PDT treatment. (C) 2018 Elsevier B.V. All rights reserved.en
dc.description.sponsorshipResearch Fund of Sakarya University [BAP-2017-02-04-013]
dc.description.urihttps://doi.org/10.1016/j.ica.2018.03.026
dc.identifier.doi10.1016/j.ica.2018.03.026
dc.identifier.eissn1873-3255
dc.identifier.endpage205
dc.identifier.issn0020-1693
dc.identifier.startpage199
dc.identifier.urihttps://hdl.handle.net/20.500.14981/57817
dc.identifier.volume477
dc.identifier.wos000429902200027
dc.language.isoeng
dc.publisherELSEVIER SCIENCE SA
dc.relation.ispartofINORGANICA CHIMICA ACTA
dc.subjectPhthalocyanine
dc.subjectSynthesis
dc.subjectZinc phthalocyanines
dc.subjectPhotochemistry
dc.subjectSINGLET OXYGEN
dc.subjectHUMAN-DISEASE
dc.subjectPHOTOSENSITIZERS
dc.subjectChemistry
dc.titlePeripherally and non-peripherally tetra-HBME (4-hydroxybenzyl methyl ether) substituted metal-free and zinc(II) phthalocyanines: Synthesis, characterization, and investigation of photophysical and photochemical properties
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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