M-hexaferrite-APTES/Pd(0) Magnetically Recyclable Nano Catalysts (MRCs)

Abstract

Magnetically recovable BaFe12O19-APTES-Pd(0) and SrFe12O19-APTES-Pd(0) catalysts were easily synthesized by immobilizing Pd nanoparticles on the surface of magnetic hexaferrite-NH2 microspheres. It was found that the combination of BaFe12O19, SrFe12O19 and 3-aminopropyltriethoxysilane (APTES) could give rise to structurally stable catalytic sites. Furthermore, BaFe12O19-APTES-Pd(0) and SrFe12O19-APTES-Pd(0) magnetically recyclable nano catalysts (MRCs) can be recovered by magnet and reused for nine runs for hydrogenation of 4-nitroaniline and dinitribenzene without significant loss in its catalytic activity which shows the indicative of a potential applications of these catalyst in industry.