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Tetrahedral Tetraphosphonic Acids. New Building Blocks in Supramolecular Chemistry

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dc.contributor.authorSchuetrumpf, Alexandra
dc.contributor.authorKirpi, Erdogan
dc.contributor.authorBulut, Aysun
dc.contributor.authorMorel, Flavien L.
dc.contributor.authorRanocchiari, Marco
dc.contributor.authorLork, Enno
dc.contributor.authorZorlu, Yunus
dc.contributor.authorGrabowsky, Simon
dc.contributor.authorYucesan, Gundog
dc.contributor.authorBeckmann, Jens
dc.date.accessioned2026-06-27T13:43:51Z
dc.date.issued2015
dc.description.abstractThe structural characterization of tetraphenylmethane tetrakis-4-phosphonic acid (4a) and its closely related Si-analogue tetraphenylsilane tetrakis-4-phosphonic acid (4b) is reported. Crystals of 4a, obtained by crystallization at 165 degrees C from water under hydrothermal conditions, comprise a dense threefold interpenetrated hydrogen-bonded network. Lower calculated density cocrystals 4b.4 EtOH, attained by recrystallization from ethanol, give rise to a porous honeycomb network that shows no interpenetration. Isolated from the mother liquor, the encapsulated ethanol is rapidly lost under ambient conditions leaving amorphous 4h. While the amorphous 4b is reasonably soluble in methanol, crystalline 4a is virtually insoluble in common organic solvents.en
dc.description.sponsorshipDeutsche Forschungsgemeinschaft (DFG) [GR4451/1-1]
dc.description.sponsorshipTurkiye Bilimsel ye Teknolojik Arastirma Kurumu [TUBITAK 212T060]
dc.description.urihttps://doi.org/10.1021/acs.cgd.5b00811
dc.identifier.doi10.1021/acs.cgd.5b00811
dc.identifier.eissn1528-7505
dc.identifier.endpage4931
dc.identifier.issn1528-7483
dc.identifier.issue10
dc.identifier.startpage4925
dc.identifier.urihttps://hdl.handle.net/20.500.14981/54580
dc.identifier.volume15
dc.identifier.wos000362628800026
dc.language.isoeng
dc.publisherAMER CHEMICAL SOC
dc.relation.ispartofCRYSTAL GROWTH & DESIGN
dc.subjectMETAL-ORGANIC FRAMEWORKS
dc.subjectSTATE COORDINATION CHEMISTRY
dc.subjectSOLID-STATE
dc.subjectINTERMOLECULAR INTERACTIONS
dc.subjectPHOSPHONATE CHEMISTRY
dc.subjectSTRUCTURAL CHEMISTRY
dc.subjectCRYSTAL-STRUCTURES
dc.subjectVOID CHANNELS
dc.subjectNETWORKS
dc.subjectDESIGN
dc.subjectChemistry
dc.subjectCrystallography
dc.subjectMaterials Science
dc.titleTetrahedral Tetraphosphonic Acids. New Building Blocks in Supramolecular Chemistry
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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