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Synthesis and characterization of soluble seco-porphyrazines with bulky substituents

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dc.contributor.authorGonca, Erguen
dc.contributor.authorKeskin, Bahadir
dc.contributor.institutionauthorKESKİN, Bahadır
dc.date.accessioned2026-06-27T13:08:10Z
dc.date.issued2009
dc.description.abstractBy cyclotetramerization of 3,4-bis(4-tert-butylphenyl)pyrroline-2,5-diimine in the presence of magnesium butanolate, magnesium porphyrazinate with eight (4-tert-butylphenyl) units on the periphery has been synthesized. Its demetalation by the treatment with trifluoroacetic acid resulted in a partially oxidized product, namely, octakis(4-tert-butylphenyl)-2-seco-porphyrazine-2,3-dione. Further reaction of this product with copper(II) acetate, zinc(II) acetate, and cobalt(II) acetate led to the metallo derivatives, [octakis(4-tert-butylphenyl)-2-seco-2, 3-dioxoporphyrazinato]M(II) (M = Cu, Zn, Co). These soluble complexes have been characterized by elemental analysis, FT-IR, 1H NMR, UV-Vis, and mass spectral data.en
dc.description.urihttps://doi.org/10.1080/00958970902962220
dc.identifier.doi10.1080/00958970902962220
dc.identifier.endpage2882
dc.identifier.issn0095-8972
dc.identifier.issue17
dc.identifier.startpage2875
dc.identifier.urihttps://hdl.handle.net/20.500.14981/50227
dc.identifier.volume62
dc.identifier.wos000268437000015
dc.language.isoeng
dc.publisherTAYLOR & FRANCIS LTD
dc.relation.ispartofJOURNAL OF COORDINATION CHEMISTRY
dc.subjectSeco-porphyrazine
dc.subject4-Tert-butylphenyl
dc.subjectPyrroline
dc.subjectCopper
dc.subjectZinc
dc.subjectCATIONIC PORPHYRINS
dc.subjectDERIVATIVES
dc.subjectASSEMBLIES
dc.subjectMAGNESIUM
dc.subjectMOIETIES
dc.subjectBRIDGES
dc.subjectChemistry
dc.titleSynthesis and characterization of soluble seco-porphyrazines with bulky substituents
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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