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A cobalt arylphosphonate MOF - superior stability, sorption and magnetism

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dc.contributor.authorZorlu, Yunus
dc.contributor.authorErbahar, Dogan
dc.contributor.authorCetinkaya, Ahmet
dc.contributor.authorBulut, Aysun
dc.contributor.authorErkal, Turan S.
dc.contributor.authorYazaydin, A. Ozgur
dc.contributor.authorBeckmann, Jens
dc.contributor.authorYucesan, Gundog
dc.date.accessioned2026-06-27T14:23:18Z
dc.date.issued2019
dc.description.abstractWe report a novel metal-organic framework (MOF) based on a cobalt arylphosphonate, namely, [Co-2(H-4-MTPPA)]center dot 3NMP center dot H2O (1.3NM center dot H2O), which was prepared solvothermically from the tetrahedral linker tetraphenylmethane tetrakis-4-phosphonic acid (H-8-MTPPA) and CoSO4 center dot 7H(2)O in N-methyl-2-pyrrolidone (NMP). Compound 1 has the highest porosity (BET surface area of 1034m(2) g(-1)) ever reported for a MOF based on an aryl phosphonic acid linker. The indigo blue crystals of 1.3NMP center dot H2O are composed of edge-shared eight-membered Co2P2O4 rings, and are thermally very stable up to 500 degrees C.en
dc.description.urihttps://doi.org/10.1039/c8cc09655d
dc.identifier.doi10.1039/c8cc09655d
dc.identifier.eissn1364-548X
dc.identifier.endpage3056
dc.identifier.issn1359-7345
dc.identifier.issue21
dc.identifier.pubmed30734794
dc.identifier.startpage3053
dc.identifier.urihttps://hdl.handle.net/20.500.14981/60031
dc.identifier.volume55
dc.identifier.wos000460731900031
dc.language.isoeng
dc.publisherROYAL SOC CHEMISTRY
dc.relation.ispartofCHEMICAL COMMUNICATIONS
dc.rightsopenAccess
dc.subjectTETRAPHOSPHONIC ACIDS
dc.subjectMETAL
dc.subjectORGANOPHOSPHONATE
dc.subjectFRAMEWORKS
dc.subjectZIRCONIUM
dc.subjectAREAS
dc.subjectChemistry
dc.titleA cobalt arylphosphonate MOF - superior stability, sorption and magnetism
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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