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Synthesis and mesomorphism of fluoroalkylated platinum complexes

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dc.contributor.authorBilgin-Eran, Belkiz
dc.contributor.authorOcak, Hale
dc.contributor.authorTschierske, Carsten
dc.contributor.authorBaumeister, Ute
dc.contributor.institutionauthorOCAK GÜMRÜKÇÜ, Hale
dc.date.accessioned2026-06-27T13:17:54Z
dc.date.issued2012
dc.description.abstractFirst examples of liquid crystalline chloro-bridged dinuclear platinum organyls carrying semiperfluorinated alkyl chains at their peripheries have been synthesised. The liquid crystalline properties were investigated using polarised optical microscopy, differential scanning calorimetry and X-ray scattering. Compounds with six semifluorinated chains and two alkyl chains show hexagonal columnar liquid crystalline phases with dramatically enhanced mesophase stabilities compared to the related hydrocarbon derivatives, which have only monotropic discotic nematic phases.en
dc.description.sponsorshipAlexander von Humboldt Foundation at Martin Luther University, Halle, Germany
dc.description.urihttps://doi.org/10.1080/02678292.2011.653413
dc.identifier.doi10.1080/02678292.2011.653413
dc.identifier.eissn1366-5855
dc.identifier.endpage476
dc.identifier.issn0267-8292
dc.identifier.issue4
dc.identifier.startpage467
dc.identifier.urihttps://hdl.handle.net/20.500.14981/51609
dc.identifier.volume39
dc.identifier.wos000302150800009
dc.language.isoeng
dc.publisherTAYLOR & FRANCIS LTD
dc.relation.ispartofLIQUID CRYSTALS
dc.subjectliquid crystals
dc.subjectmetallomesogens
dc.subjectfluoroalkylated metallomesogens
dc.subjectplatinum organyls
dc.subjectortho-metallation
dc.subjectANTIFERROELECTRIC IMINE LIGANDS
dc.subjectLIQUID-CRYSTALLINE PROPERTIES
dc.subjectORTHO-METALATED MESOGENS
dc.subjectMICRO-SEGREGATION
dc.subjectPALLADIUM(II) COMPLEXES
dc.subjectMOLECULAR-STRUCTURE
dc.subjectBLOCK MOLECULES
dc.subjectCOLUMNAR
dc.subjectMESOPHASES
dc.subjectChemistry
dc.subjectCrystallography
dc.subjectMaterials Science
dc.titleSynthesis and mesomorphism of fluoroalkylated platinum complexes
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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