Yayın:
Poly(ethylene glycol)-Thioxanthone Prepared by Diels-Alder Click Chemistry as One-Component Polymeric Photoinitiator for Aqueous Free-Radical Polymerization

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dc.contributor.authorAkat, Hakan
dc.contributor.authorGacal, Burcin
dc.contributor.authorBalta, Demet Karaca
dc.contributor.authorArsu, Nergis
dc.contributor.authorYagci, Yusuf
dc.contributor.institutionauthorARSU, Nergis
dc.date.accessioned2026-06-27T12:52:23Z
dc.date.issued2010
dc.description.abstractNovel water-borne macrophotoinitiator containing thioxanthone (TX) end group was successfully synthesized by using Die Is Alder (DA) [4 + 2] click chemistry strategy. For this purpose, thioxanthone-anthracene (TX-A) and maleimide end-functionalized poly(ethylene glycol) (PEG-MI) were reacted in toluene at reflux temperature for 48 h. The final polymer (PEG-TX) and the intermediates were characterized in detail by spectral analysis. PEG-TX possesses absorption characteristics similar to the parent TX. The one-component photoinitiating nature of the photointiator was demonstrated by photopolymeization of several hydrophilic vinyl monomers, such as acrylic acid, acrylamide, 2-hydroxyethyl acrylate, and 1-vinyl-2-pyrrolidone. (C) 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2109-2114, 2010en
dc.description.sponsorshipIstanbul Technical University
dc.description.sponsorshipTubitak
dc.description.urihttps://doi.org/10.1002/pola.23978
dc.identifier.doi10.1002/pola.23978
dc.identifier.eissn1099-0518
dc.identifier.endpage2114
dc.identifier.issn0887-624X
dc.identifier.issue10
dc.identifier.startpage2109
dc.identifier.urihttps://hdl.handle.net/20.500.14981/47699
dc.identifier.volume48
dc.identifier.wos000277423000006
dc.language.isoeng
dc.publisherWILEY
dc.relation.ispartofJOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
dc.subjectaqueous free-radical polymerization
dc.subjectclick chemistry
dc.subjectDiels Alder cycloaddition
dc.subjectmacrophotoinitiator
dc.subjectphotopolymerization
dc.subjectthioxanthone
dc.subjectIN-CHAIN THIOXANTHONE
dc.subjectCOINITIATOR AMINE
dc.subject1,3-DIPOLAR CYCLOADDITIONS
dc.subjectBLOCK-COPOLYMERS
dc.subjectTERMINAL ALKYNES
dc.subjectBENZOPHENONE
dc.subjectAZIDES
dc.subjectATRP
dc.subjectPolymer Science
dc.titlePoly(ethylene glycol)-Thioxanthone Prepared by Diels-Alder Click Chemistry as One-Component Polymeric Photoinitiator for Aqueous Free-Radical Polymerization
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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