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Thioxanthone-anthracene: A new photoinitiator for free radical polymerization in the presence of oxygen

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dc.contributor.authorBalta, Demet Karaca
dc.contributor.authorArsu, Nergis
dc.contributor.authorYagci, Yusuf
dc.contributor.authorJockusch, Steffen
dc.contributor.authorTurro, Nicholas J.
dc.contributor.institutionauthorARSU, Nergis
dc.date.accessioned2026-06-27T13:05:39Z
dc.date.issued2007
dc.description.abstractA novel thioxanthone-anthracene (TX-A) photoinitiator, namely 5-thia-pentacene-14-one, possessing the respective photochromic groups was synthesized. TX-A is an efficient photoinitiator for free radical polymerization of acrylic and styrenic type monomers in the presence of oxygen. UV-vis, FT-IR, and fluorescence spectroscopic and polymerization studies revealed that photoinitiation occurs through anthracene chromophore. In contrast to thioxanthone-based photoinitiators, TX-A does not require an additional hydrogen donor for the initiation.en
dc.description.urihttps://doi.org/10.1021/ma0628735
dc.identifier.doi10.1021/ma0628735
dc.identifier.endpage4141
dc.identifier.issn0024-9297
dc.identifier.issue12
dc.identifier.startpage4138
dc.identifier.urihttps://hdl.handle.net/20.500.14981/49630
dc.identifier.volume40
dc.identifier.wos000247138500011
dc.language.isoeng
dc.publisherAMER CHEMICAL SOC
dc.relation.ispartofMACROMOLECULES
dc.subjectPHOTO-CROSS-LINKING
dc.subjectELECTRON-TRANSFER
dc.subjectSYSTEMS
dc.subjectENDOPEROXIDES
dc.subjectDERIVATIVES
dc.subjectPolymer Science
dc.titleThioxanthone-anthracene: A new photoinitiator for free radical polymerization in the presence of oxygen
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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