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Synthesis of 4′-acetyl(benzo-15-crown-5)-oxime and its complexes with copper(II), nickel(II), cobalt(II) and uranyl(VI)

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dc.contributor.authorAvciata, U
dc.contributor.authorDemirhan, N
dc.contributor.authorBozdogan, AE
dc.date.accessioned2026-06-27T12:56:14Z
dc.date.issued1998
dc.description.abstractA new macrocyclic ligand (HL) has been synthesized by the reaction of 4'-acetyl(benzo-15-crown-5) with hydroxylamine hydrochloride. The copper(II), nickel(II), cobalt(II) and uranyl(VI) complexes of the 4'-acetyl(benzo-15-crown-5)oxime (16-acetylhydroxyimino-2,3,5,6,8,9,11,12-octahydrobenzo(1,4,7,10,13)pentaoxacyclopentadecine) have been prepared, characterized and studied potentiometrically at 25 degrees C, I = 1.0 M KNO3. Protonation constants of the ligand and overall formation constants have been calculated from potentiometric data using the program TITFIT.en
dc.identifier.endpage403
dc.identifier.issn0094-5714
dc.identifier.issue3
dc.identifier.startpage393
dc.identifier.urihttps://hdl.handle.net/20.500.14981/47866
dc.identifier.volume28
dc.identifier.wos000073062500006
dc.language.isoeng
dc.publisherMARCEL DEKKER INC
dc.relation.ispartofSYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
dc.subjectChemistry
dc.titleSynthesis of 4′-acetyl(benzo-15-crown-5)-oxime and its complexes with copper(II), nickel(II), cobalt(II) and uranyl(VI)
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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