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ESTIMATION OF THE EQUATION OF STATE EXCHANGE ENERGY AND ENTROPY PARAMETERS OF A POLYMER SOLVENT PAIR BY INTRINSIC-VISCOSITY MEASUREMENTS

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dc.contributor.authorYILMAZ, F
dc.contributor.authorBAYSAL, BM
dc.contributor.institutionauthorBAYSAL, Mustafa
dc.contributor.institutionauthorYILMAZ, Ayçe Feride
dc.date.accessioned2026-06-27T12:58:34Z
dc.date.issued1993
dc.description.abstractThe intrinsic viscosity data of linear poly(4-chlorostyrene) in n-propylbenzene and isopropylbenzene were used to estimate the equation of state exchange energy (X12) and entropy (Q12) parameters. The quantities estimated for X12 were 6.7 and 8.1 J cm-3 and those of Q12 were -0.069 and -0.063 J cm-3 deg-1 in n-propylbenzene and isopropylbenzene, respectively. The average values of the chain unperturbed dimension constant (K0) and the characteristic ratio (C(infinity)) were found to be 0.55 x 10(-3) dl mol1/2 g-3/2 and 10.54, respectively, from the intrinsic viscosities measured at the corresponding theta-temperatures.en
dc.description.urihttps://doi.org/10.1002/pi.4990310115
dc.identifier.doi10.1002/pi.4990310115
dc.identifier.endpage111
dc.identifier.issn0959-8103
dc.identifier.issue1
dc.identifier.startpage107
dc.identifier.urihttps://hdl.handle.net/20.500.14981/48425
dc.identifier.volume31
dc.identifier.wosA1993KN26100014
dc.language.isoeng
dc.publisherJOHN WILEY & SONS LTD
dc.relation.ispartofPOLYMER INTERNATIONAL
dc.subjectPOLY(4-CHLOROSTYRENE)
dc.subjectINTRINSIC VISCOSITY
dc.subjectPOLYMER SOLVENT INTERACTIONS
dc.subjectEQUATION OF STATE PARAMETERS
dc.subjectPOLYSTYRENE SOLUTIONS
dc.subjectTHERMODYNAMICS
dc.subjectPolymer Science
dc.titleESTIMATION OF THE EQUATION OF STATE EXCHANGE ENERGY AND ENTROPY PARAMETERS OF A POLYMER SOLVENT PAIR BY INTRINSIC-VISCOSITY MEASUREMENTS
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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