Solar-Driven Remediation of Complex Cationic Dye Mixtures Using α-Fe2O3/ZnFe2O4 Heterocatalyst Under Sunlight: Insights from Single and Binary Systems

Abstract

In the current investigation, the solar photocatalytic degradation of two cationic model dyes (methyl green (MG) and crystal violet (CV)) was studied using alpha-Fe2O3/ZnFe2O4 nanocomposite. The fine powder of nanoparticles was obtained by co-precipitation method at pH = 10 and characterized by X-ray diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM) and UV-vis spectroscopy. The surface properties were further examined through temperature-programmed desorption (TPD) and point of zero charge (PZC) measurements to assess the acid-base characteristics and surface charge behavior of the material. Adsorption and photocatalytic performance were systematically evaluated in both single and binary systems. Dark adsorption experiments showed a better affinity of the alpha-Fe2O3/ZnFe2O4 heterosystem towards MG dye in both cases. Under natural sunlight irradiation in the individual system, the photocatalytic activity of the nanoparticles was significantly higher for MG (81.67% removal) compared to CV (41.70%). Kinetics analysis revealed that the photodegradation of both dyes followed a pseudo-first-order model. In binary systems, competitive adsorption effects strongly influenced the degradation behavior, with MG showing preferential adsorption and higher degradation rates. Moreover, the MG discoloration kinetics followed a second-order model, while CV kinetics transitioned from second- to zero-order with increased initial concentration.