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Photopolymerization of acrylamide with benzophenone/methylated-β-cyclodextrin inclusion complex in the presence of jeffamine based dendrimers as coinitiators in aqueous media

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dc.contributor.authorTemel, Gokhan
dc.contributor.authorParali, Tezcan
dc.contributor.authorTulu, Metin
dc.contributor.authorArsu, Nergis
dc.contributor.institutionauthorARSU, Nergis
dc.date.accessioned2026-06-27T12:51:49Z
dc.date.issued2010
dc.description.abstractBP/Me-beta-CD inclusion complex was synthesized and used in photoinduced free radical polymerization of acrylamide as a type II photoinitiator in the presence of a dendritic co-initiator. Characterization and photophysical studies of the inclusion complex were determined by H-1 NMR, UV, laser flash photolysis and phosphorescence spectroscopy. According to acrylamide polymerization of the BP/Me-beta-CD water soluble photoinitiator, BP/Me-beta-CD initiates polymerization of acrylamide effectively with six and twelve armed dendritic co-initiators in aqueous media. The 24 armed dendritic co-initiator was not as efficient as the six and twelve armed dendritic co-initiators with the BP/Me-beta-CD inclusion complex, due to the sterical hindrance of the amine groups in the co-initiator. (C) 2010 Elsevier B.V. All rights reserved.en
dc.description.sponsorshipTUBITAK
dc.description.sponsorshipDPT
dc.description.sponsorshipYildiz Technical University Research Foundation
dc.description.urihttps://doi.org/10.1016/j.jphotochem.2010.04.018
dc.identifier.doi10.1016/j.jphotochem.2010.04.018
dc.identifier.endpage51
dc.identifier.issn1010-6030
dc.identifier.issue1
dc.identifier.startpage46
dc.identifier.urihttps://hdl.handle.net/20.500.14981/47576
dc.identifier.volume213
dc.identifier.wos000279969400007
dc.language.isoeng
dc.publisherELSEVIER SCIENCE SA
dc.relation.ispartofJOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
dc.subjectBenzophenone
dc.subjectWater soluble photoinitiator
dc.subjectCyclodextrin
dc.subjectDendrimer
dc.subjectFree radical polymerization
dc.subjectPOLY(PROPYLENE IMINE) DENDRIMERS
dc.subjectFREE-RADICAL POLYMERIZATION
dc.subjectHOST/GUEST COMPLEX
dc.subjectPHOTOCHEMISTRY
dc.subjectWATER
dc.subjectChemistry
dc.titlePhotopolymerization of acrylamide with benzophenone/methylated-β-cyclodextrin inclusion complex in the presence of jeffamine based dendrimers as coinitiators in aqueous media
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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