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Claisen type Condensation of Methyl Ketones with Carbimidothioates: A New Gateway for the Synthesis of β-Enaminones

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dc.contributor.authorSwaroop, Toreshettahally R.
dc.contributor.authorRangappa, Kanchugarakoppal S.
dc.contributor.authorTorun, Lokman
dc.date.accessioned2026-06-27T14:33:08Z
dc.date.issued2021
dc.description.abstractCarbimidothioates are synthesized by the reaction of Grignard reagents or heteroaryl lithium compounds with arylisothiocyanates followed by treatment with methyl iodide. Further, application of these intermediates in the synthesis of beta-enaminones by their condensation with methyl ketones in the presence of sodium hydride in DMF is reported. This method offers a new gateway for the synthesis of beta-enaminones, which are important building blocks in synthetic organic chemistry.en
dc.description.sponsorship2221 program of TUBITAK [21514107-115.02-E.170100]
dc.description.sponsorshipOffice of Scientific Research of Yildiz Technical University [3991, FBA-2020-3991]
dc.description.urihttps://doi.org/10.1002/slct.202004295
dc.identifier.doi10.1002/slct.202004295
dc.identifier.endpage180
dc.identifier.issn2365-6549
dc.identifier.issue2
dc.identifier.startpage177
dc.identifier.urihttps://hdl.handle.net/20.500.14981/61970
dc.identifier.volume6
dc.identifier.wos000607604000003
dc.language.isoeng
dc.publisherWILEY-V C H VERLAG GMBH
dc.relation.ispartofCHEMISTRYSELECT
dc.subjectcarbimidothioates
dc.subjectbeta-enaminones
dc.subjectgrignard reagents
dc.subjectmethyl ketones
dc.subjectorganolithium compounds
dc.subjectCATALYZED CYCLIZATION
dc.subjectBOND FORMATION
dc.subjectALPHA,BETA-UNSATURATED KETONES
dc.subjectALPHA-OXODITHIOESTERS
dc.subjectXANTHATE ESTERS
dc.subjectACID
dc.subjectISOCYANIDES
dc.subjectEFFICIENT
dc.subjectBASE
dc.subjectFUNCTIONALIZATION
dc.subjectChemistry
dc.titleClaisen type Condensation of Methyl Ketones with Carbimidothioates: A New Gateway for the Synthesis of β-Enaminones
dc.typeArticle
dspace.entity.typePublication
local.import.sourceWOS

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